丁二硫醚

化合物

丁二硫醚二丁基二硫是一种有机化合物,化学式为C8H18S2。它可由正丁硫醇的氧化反应制得。[4]它在二氯甲烷中可以被间氯过氧苯甲酸氧化,生成丁基硫代亚磺酸-S-丁酯。[5]它和溴化苄三氯化铝催化下反应,可以得到苄基丁硫醚。[6]

丁二硫醚
别名 二丁基二硫
二正丁基二硫
二正丁基二硫醚
识别
CAS号 629-45-8  checkY
性质
化学式 C8H18S2
摩尔质量 178.36 g·mol⁻¹
密度 0.930 g·cm−3(20 °C)[1]
熔点 116—118 °C(389—391 K)[2]
沸点 228—230 °C(501—503 K)[3]
相关物质
相关化学品 丁硫醚日语ジブチルスルフィド
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Gilman, Henry; Smith, Lloyd E.; Parker, Harold H. THE CONSTITUTION OF DISULFOXIDES. Journal of the American Chemical Society (American Chemical Society (ACS)). 1925, 47 (3): 851–860. ISSN 0002-7863. doi:10.1021/ja01680a037. 
  2. ^ Habib Firouzabadi, Daryoush Mohajer, Mohsen Entezari-Moghadam. Barium Ferrate Monohydrate BaFeO 4 ·H 2 O, a Useful Oxidant for the Oxidation of Organic Compounds under Aprotic Conditions. Bulletin of the Chemical Society of Japan. 1988-06, 61 (6): 2185–2189 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.61.2185. (原始内容存档于2021-12-02) (英语). 
  3. ^ Hisashi Fujihara, Ryouichi Akaishi, Naomichi Furukawa. A Mild, High-Yield Conversion of Thiols into Disulfides Using Disulfide Dication Salt: A New Redox System. Bulletin of the Chemical Society of Japan. 1989-02, 62 (2): 616–617 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.62.616. (原始内容存档于2021-12-02) (英语). 
  4. ^ Abhinandan D. Hudwekar, Praveen K. Verma, Jaspreet Kour, Shilpi Balgotra, Sanghapal D. Sawant. Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazoles, and Disulfides: Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazole. European Journal of Organic Chemistry. 2019-02-14, 2019 (6): 1242–1250 [2021-12-10]. doi:10.1002/ejoc.201801610 (英语). 
  5. ^ Jinyue Su, Yatao Qiu, Kun Ma, Yiwu Yao, Zhen Wang, Xianling Li, Dayong Zhang, Zhengchao Tu, Sheng Jiang. Design, synthesis, and biological evaluation of largazole derivatives: alteration of the zinc-binding domain. Tetrahedron. 2014-10, 70 (42): 7763–7769 [2021-12-10]. doi:10.1016/j.tet.2014.05.078. (原始内容存档于2018-07-01) (英语). 
  6. ^ M. M. Lakouraj, B. Movassagh, Z. Fadaei. SYNTHESIS OF ORGANIC SULFIDES VIA Zn/AlCl 3 SYSTEM IN AQUEOUS MEDIA. Synthetic Communications. 2002-01, 32 (8): 1237–1242 [2021-12-10]. ISSN 0039-7911. doi:10.1081/SCC-120003615 (英语).