六氰合钴(III)酸铊(I)

六氰合钴(III)酸铊(I)是一种配位化合物,化学式为Tl3[Co(CN)6],它具有f.c.c.晶格,空间群Fm3m。[2]它可由六氰合钴(III)酸碳酸亚铊反应得到,[3]它也可由氰化钴氰化亚铊俄语ианид таллия(I)溶液反应,再对溶液加热得到:[4]

六氰合钴(III)酸铊(I)
识别
CAS号 14896-54-9  checkY
性质
化学式 Tl3[Co(CN)6]
摩尔质量 828.19 g·mol⁻¹
溶解性 10.04 pts/100 pts H2O[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。
Co(CN)2 + 4 TlCN → Tl4Co(CN)6
2 Tl4Co(CN)6 + 2 H2O → 2 Tl3Co(CN)6 + 2 TlOH + H2

参考文献

  1. ^ A dictionary of chemical solubilities: inorganic. 1896. pp 131. Thallium cobalticyanide, Tl3Co(CN)6.
  2. ^ Dragulescu, C.; Tribunescu, P. Structure of the simple and mixed cobalticyanides of silver and thallium(法文). Rev. Chim. Minerale, 1965. 2 (1): 119-125.
  3. ^ P. S. Braterman, P. B. P. Phipps and R. J. P. Williams. 1147. Charge-transfer phenomena in some inorganic complexes. Part I. Electronic conduction in some complex cyanides. J. Chem. Soc., 1965, 6164-6169. doi:10.1039/JR9650006164
  4. ^ Sianokomplekse. South African Journal of Chemistry, 1966. 19 (2). doi:10.10520/AJA03794350_1157