十钨二钒磷酸

十钨二钒磷酸是一种杂多酸,化学式为H5PW10V2O40[3]它可以偏钒酸钠磷酸氢二钠钨酸钠硫酸为原料反应制得。[1]它可以被还原剂还原为低价态化合物。[4]它可用作无溶剂乙酰化的催化剂。[1]它可被封装进rht-MOF-1的空腔内用于燃料油的脱[5]

十钨二钒磷酸
英文名 10-Tungsto-2-vanadophosphoric acid
识别
CAS号 12398-74-2  checkY
性质
化学式 H5O40PV2W10
摩尔质量 2616.27 g·mol−1
外观 橙红色固体[1]
结构
晶体结构 立方晶系 O2h-Pn3n(三十水合物)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 1.2 Farhadi, Saeid; Taherimehr, Masoumeh. Vanadium-substituted tungstophosphoric acid (H5PV2W10O40)​: a green and reusable catalyst for highly efficient acetylation of alcohols and phenols under solvent-free conditions页面存档备份,存于互联网档案馆). Acta Chimica Slovenica, 2008. 55 (3): 637-643.
  2. ^ Suteu, Alexandru; Mirza, Lucretia. X-ray structural study of triheteropolyacids(法文). Revue Roumaine de Chimie, 1970. 15 (10): 1563-1572.
  3. ^ Courtin, Paul. Molybdenum and tungsten heteropolyanions substituted by vanadium(V)​. II. Compounds with high vanadium content(法文). Revue de Chimie Minerale, 1971. 8 (2): 221-240.
  4. ^ Polotebnova, N. A.; Krachun, S. V.; Danilina, L. M. Products of the reduction of tungstovanadophosphoric heteropoly acids(俄文). Zhurnal Neorganicheskoi Khimii, 1976. 21 (11): 3172-3175.
  5. ^ Yiyang Bai, Yuxiang Xin, Jiabin Liu, Liqiang Ma, Guangming Li. Construction of H 6 PW 9 V 3 O 40 @ rht ‐MOF‐1 for deep oxidative desulfurization of fuel oil. Applied Organometallic Chemistry. 2022-05, 36 (5) [2022-09-24]. ISSN 0268-2605. doi:10.1002/aoc.6633. (原始内容存档于2022-09-27) (英语).