氟二氯碘甲烷

氟二氯碘甲烷是一种有机化合物,化学式为CCl2FI。它可由氟二氯甲烷溴化,生成氟二氯溴甲烷,再在丙酮中与碘化钠进行卤素交换得到;[2]或通过三(二甲氨基)(氟二氯甲基)氯化𬭸和一氯化碘的反应得到。[3]它在室温不稳定,易析出碘。[4]

氟二氯碘甲烷
英文名 Dichlorofluoroiodomethane
别名 二氯氟碘甲烷
识别
CAS号 420-48-4  checkY
性质
化学式 CCl2FI
摩尔质量 228.82 g·mol−1
熔点 −107 °C[1]
沸点 90 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-10-27].
  2. ^ Miller, W.T.; M.W. Kellogg Company; United States. Army; Cornell University. Basic Studies on the Chemistry of Fluorine Compounds. Office of Technical Services, United States Department of Commerce. 1954 [2021-10-27]. (原始内容存档于2021-10-27). 
  3. ^ D.J. Burton, S. Shin-ya, H.S. Kesling. Preparation of halo--methanes potassium fluoride-halogen cleavage of halo--methylphosphonium salts. Journal of Fluorine Chemistry. 1982-03, 20 (1): 89–97 [2021-10-27]. doi:10.1016/S0022-1139(00)84021-X. (原始内容存档于2018-06-18) (英语). 
  4. ^ Katritzky, A.R.; Gilchrist, T.L.; Meth-Cohn, O.; Rees, C.W. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations. Elsevier Science. 1995: 225 [2021-10-27]. ISBN 978-0-08-042704-1. (原始内容存档于2021-10-29).  |issue=被忽略 (帮助)