氯化羰基(四氟乙烯)二(三苯基膦)合铱

氯化羰基(四氟乙烯)二(三苯基膦)合铱
识别
CAS号	12120-26-2
SMILES	O#C[Ir+]1([Cl-])(C(F)(F)=C1(F)F)([P](C=2C=CC=CC2)(C=3C=CC=CC3)C=4C=CC=CC4)[P](C=5C=CC=CC5)(C=6C=CC=CC6)C=7C=CC=CC7;
性质
化学式	C39H30ClF4IrOP2
摩尔质量	880.27 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氯化羰基(四氟乙烯)二(三苯基膦)合铱是一种有机铱化合物，化学式为(PPh₃)₂Ir(C₂F₄)(CO)Cl，其中Ph为苯基。它可由氯化羰基二(三苯基膦)铱在苯中和四氟乙烯反应制得。^[1]它在100 °C分解放出四氟乙烯。^[2]它和SFO₂(OCH₃)反应，可以得到白色的IrCH₃(CO)Cl(PPh₃)₂(SFO₃)。^[3]

参考文献

^ Cramer R, Parshall G W. Tetrafluoroethylene Complexes of Transition Metals. Journal of the American Chemical Society, 1965, 87(6): 1392-1393. doi:10.1021/ja01084a048
^ Parshall G W, Jones F N. Fluoroolefin Complexes of Transition Metals. Journal of the American Chemical Society, 1965, 87(23): 5356-5361. doi:10.1021/ja00951a017.
^ Eaborn C, Farrell N, Murphy J L, et al. Reactions of methyl fluorosulphate and triethyloxonium tetrafluoroborate with transition-metal complexes. Journal of the Chemical Society, Dalton Transactions, 1976 (1): 58-67. doi:10.1039/DT9760000058.

[1] Cramer R, Parshall G W. Tetrafluoroethylene Complexes of Transition Metals. Journal of the American Chemical Society, 1965, 87(6): 1392-1393. doi:10.1021/ja01084a048

[2] Parshall G W, Jones F N. Fluoroolefin Complexes of Transition Metals. Journal of the American Chemical Society, 1965, 87(23): 5356-5361. doi:10.1021/ja00951a017.

[3] Eaborn C, Farrell N, Murphy J L, et al. Reactions of methyl fluorosulphate and triethyloxonium tetrafluoroborate with transition-metal complexes. Journal of the Chemical Society, Dalton Transactions, 1976 (1): 58-67. doi:10.1039/DT9760000058.

[1]

[2]

[3]

氯化羰基(四氟乙烯)二(三苯基膦)合铱
识别
CAS号	12120-26-2 ^Y
SMILES	O#C[Ir+]1([Cl-])(C(F)(F)=C1(F)F)([P](C=2C=CC=CC2)(C=3C=CC=CC3)C=4C=CC=CC4)[P](C=5C=CC=CC5)(C=6C=CC=CC6)C=7C=CC=CC7
性质
化学式	C₃₉H₃₀ClF₄IrOP₂
摩尔质量	880.27 g·mol⁻¹
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。