氯烯炔菊酯

化合物

氯烯炔菊酯是一种有机化合物,化学式为C16H20Cl2O2。它是一种拟除虫菊酯杀虫剂,对蚊、蝇具有触杀活性。[1]它可由3-(2,2-二氯乙烯基)-2,2,-二甲基环丙酰氯(二氯菊酰氯)和4-甲基-4-庚烯-1-炔-3-醇在碳酸钾的存在下反应得到。[3][4]

氯烯炔菊酯
识别
CAS号 54407-47-5  checkY
SMILES
 
  • CCC=C(C)C(C#C)OC(=O)C1C(C)(C)C1C=C(Cl)Cl
性质
化学式 C16H20Cl2O2
摩尔质量 315.23 g·mol−1
外观 淡黄色油状液体[1]
密度 1.192±0.06 g·cm−3[2]
沸点 385.3±42.0 °C[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 氯烯炔菊酯. ChemicalBook. [2020-07-01]. (原始内容存档于2020-07-03). 
  2. ^ 2.0 2.1 Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-07-01]
  3. ^ Hidefumi Nakatsuji, Jun-ichi Morita, Tomonori Misaki, Yoo Tanabe. Water Solvent Method for Esterification and Amide Formation between Acid Chlorides and Alcohols Promoted by Combined Catalytic Amines: Synergy betweenN-Methylimidazole andN,N,N′,N′-Tetramethylethylenediamine (TMEDA). Advanced Synthesis & Catalysis. 2006-10, 348 (15): 2057–2062 [2020-07-01]. doi:10.1002/adsc.200600256 (英语). 
  4. ^ Hidefumi Nakatsuji, Mami Morimoto, Tomonori Misaki, Yoo Tanabe. Mild, powerful, and robust methods for esterification, amide formation, and thioesterification between acid chlorides and alcohols, amines, thiols, respectively. Tetrahedron. 2007-11, 63 (48): 12071–12080 [2020-07-01]. doi:10.1016/j.tet.2007.08.117 (英语).