硫代酸盐矿物
硫代酸盐矿物是指化学组成具有通式AmBnSp的一类矿物,其中A是金属元素,例如铜、铅、銀、铁、汞、锌、钒,B通常是类金属元素,例如砷、锑、铋,罕见锗,或者金属元素如锡、罕见钒。S可以是硫,也可以是同属硫族的硒、碲。[1]在尼克尔-斯特伦茨分类中硫代酸盐矿物归于“硫化物与硫代酸盐矿物”集合。[1]
![](http://images.weserv.nl/?url=//upload.wikimedia.org/wikipedia/commons/thumb/a/a9/Proustite.jpg/267px-Proustite.jpg)
列表
已发现的硫代酸盐矿物有200来种。一些例子有:[2]
- A3BX3类
- A3BX4类
- A2BX3类
- ABX2类
- A2B2X5类
- A2B3X6类
- AB2X4类
合成硫代酸盐
实验室合成能制备自然界中未发现过的硫代酸盐化合物结晶。[3]
参考资料
- ^ 1.0 1.1 Strunz classification of sulfides and sulfosalts. Mindat. [2017-03-14]. (原始内容存档于2020-05-16).
- ^ Palache, C., H. Berman, and C. Frondel (1944) Dana’s System of Mineralogy, (7th edition), v. I, pp. 348-350
- ^ Sheldrick, William S.; Wachhold, Michael "Chalcogenidometalates of the heavier Group 14 and 15 elements" Coordination Chemistry Reviews 1998, vol. 176, 211-322. doi:10.1016/S0010-8545(98)00120-9
- N.N. Mozgova, 2000, Sulfosalt mineralogy today in Modern Approaches to Ore and Environmental Mineralogy, MSF Mini-Symposium Espoo Finland, June 11–17, 2000, https://web.archive.org/web/20050907172937/http://www.igem.ru/igem/mine/sulfosalts.htm Retrieved July 22, 2005.
- Moëlo, Yves; Makovicky, Emil; Mozgova, Nadejda N.; Jambor, John L.; Cook, Nigel; Pring, Allan; Paar, Werner; Nickel, Ernest H.; et al. Sulfosalt systematics: a review. Report of the sulfosalt sub-committee of the IMA Commission on Ore Mineralogy (PDF). European Journal of Mineralogy. 2008, 20 (1): 7 [2017-03-14]. doi:10.1127/0935-1221/2008/0020-1778. (原始内容 (PDF)存档于2017-08-08).
- Stuart J. Mills; Frédéric Hatert; Ernest H. Nickel & Giovanni Ferraris. The standardisation of mineral group hierarchies: application to recent nomenclature proposals (PDF). Eur. J. Mineral. 2009, 21 (5): 1073–1080 [2017-03-14]. doi:10.1127/0935-1221/2009/0021-1994. (原始内容 (PDF)存档于2011-02-17).
- Ernest H. Nickel & Monte C. Nichols. IMA-CNMNC List of Mineral Names (PDF). IMA-CNMNC. March 2009 [2017-03-14]. (原始内容 (PDF)存档于2009-03-20).
- Ferraiolo, Jim. Nickel–Strunz (Version 10) Classification System. webmineral.com. [2017-03-14]. (原始内容存档于2012-07-19).