1,2-二吗啉基乙烷

化合物

1,2-二吗啉基乙烷(DME)是一种有机化合物,化学式为C10H20N2O2。它可由吗啉1,2-二溴乙烷回流反应制得。[2]它是一种配体,可以和氯化锌硝酸镍在甲醇中反应,得到Zn(DME)Cl2或Ni(DME)(NO3)2[3]

1,2-二吗啉基乙烷
识别
CAS号 1723-94-0  checkY
PubChem 72888
ChemSpider 65720
SMILES
 
  • C1COCCN1CCN2CCOCC2
性质
化学式 C10H20N2O2
摩尔质量 200.28 g·mol−1
外观 白色固体[1]
危险性
GHS危险性符号
《全球化学品统一分类和标签制度》(简称“GHS”)中腐蚀性物质的标签图案《全球化学品统一分类和标签制度》(简称“GHS”)中有害物质的标签图案
GHS提示词 危险
H-术语 H315, H317, H318, H319, H335
P-术语 P261, P264, P264+265, P271, P272, P280, P302+352, P304+340, P305+351+338, P305+354+338, P317, P319, P321, P332+317
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Peter W. Moore, Yanxiao Jiao, Paul M. Mirzayans, Lexter Ng Qi Sheng, Jordan P. Hooker, Craig M. Williams. Selectivity Modulation of the Ley–Griffith TPAP Oxidation with N ‐Oxide Salts. European Journal of Organic Chemistry. 2016-07, 2016 (20): 3401–3407 [2023-06-26]. ISSN 1434-193X. doi:10.1002/ejoc.201600453 (英语). 
  2. ^ Yaohong Zhao, Shunyou Cai, Jing Li, David Zhigang Wang. Visible-light photo-catalytic C–C bond cleavages: preparations of N,N-dialkylformamides from 1,2-vicinal diamines. Tetrahedron. 2013-09, 69 (38): 8129–8131 [2023-06-26]. doi:10.1016/j.tet.2013.07.056. (原始内容存档于2021-03-08) (英语). 
  3. ^ Hamid Goudarziafshar, Majid Rezaeivala, Fayezeh Khosravi, Yunes Abbasityula, Somaieh Yousefi, Neslihan Özbek, Václav Eigner, Michal Dušek. Synthesis, characterization and crystal structures of new Zinc(II) and Nickel(II) complexes containing morpholine moiety and their antibacterial studies. Journal of the Iranian Chemical Society. 2015-01, 12 (1): 113–119 [2023-06-26]. ISSN 1735-207X. doi:10.1007/s13738-014-0462-2 (英语).