1,3-二乙烯基苯

1,3-二乙烯基苯是一种有机化合物,化学式为C10H10。它可由1,3-二碘苯四乙烯基硅催化下反应得到。[2]1,3-苯二甲醛三苯基甲基溴化𬭸叔丁醇钾的存在下反应,也能得到1,3-二乙烯基苯。[3]它和溴反应,根据反应条件不同,可以得到1,5-二溴-2,4-二乙烯基苯[4]或1,3-二(1,2-二溴乙基)苯[5]。它和苯甲酰胺氢氧化钾二甲基亚砜中于120 °C反应,可以得到N,N'-(1,3-苯二亚基-2,1-乙二基)二苯甲酰胺。[6]

1,3-二乙烯基苯
识别
CAS号 108-57-6  checkY
性质
化学式 C10H10
摩尔质量 130.19 g·mol−1
熔点 −52.3 °C(220.8 K)[1]
沸点 121 °C(394 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-06-30].
  2. ^ Abdessamad Grirrane, Hermenegildo Garcia, Avelino Corma. Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C–C coupling of vinylsilanes and halobenzenes leading to styrenes. Journal of Catalysis. 2013-06, 302: 49–57 [2021-06-30]. doi:10.1016/j.jcat.2013.02.019. (原始内容存档于2018-06-11) (英语). 
  3. ^ Shunsuke Tanaka, Masayoshi Matsumoto, Raita Goseki, Takashi Ishizone, Akira Hirao. Living Anionic Polymerization of 1,4-Divinylbenzene and Its Isomers. Macromolecules. 2013-01-08, 46 (1): 146–154 [2021-06-30]. ISSN 0024-9297. doi:10.1021/ma302246u (英语). 
  4. ^ Cui, Aijun; Tian, Junkai; Liu, Liu; Li, Jing; Chen, Qun; He, Mingyang. Preparation of 1,3-divinyl-4,6-benzenedicarboxylic acid oxygen absorbents for oxygen-absorbing polyester. 2012. CN 102746496 A.
  5. ^ Mitchell, Reginald H.; Ghose, Bhupendra N.; Williams, Mary E. The intra- and intermolecular copper (I) catalyzed couplings of vinyl Grignards. A facile synthesis of pleiadiene and a synthesis of a conjugated 14-membered ring system. Canadian Journal of Chemistry. 1977, 55 (2): 210–219. ISSN 0008-4042. doi:10.1139/v77-035. 
  6. ^ Ayushee, Monika Patel, Priyanka Meena, Kousar Jahan, Prasad V. Bharatam, Akhilesh K. Verma. Base-Mediated Anti-Markovnikov Hydroamidation of Vinyl Arenes with Arylamides. Organic Letters. 2021-01-15, 23 (2): 565–570 [2021-06-30]. ISSN 1523-7060. doi:10.1021/acs.orglett.0c04084 (英语).