1,5-二羟基蒽醌

化合物

1,5-二羟基蒽醌是一种有机化合物,化学式为(C
6
H
3
OH)
2
(CO)
2
,它是二羟基蒽醌同分异构体之一,为橙色固体。它是传统中药的成分之一。[2]它可以和过渡金属螯合配位。[3]

1,5-二羟基蒽醌
别名 1,5-dihydroxy-9,10-anthracenedione, 1,5-dihydroxyanthraquinone, Anthrarufin
识别
CAS号 117-12-4  checkY
PubChem 8328
ChemSpider 8025
SMILES
 
  • C1=CC2=C(C(=C1)O)C(=O)C3=C(C2=O)C(=CC=C3)O
Beilstein 1881718
Gmelin 144152
ChEBI 37501
性质
化学式 C14H8O4
摩尔质量 240.21 g·mol−1
外观 橙色固体[1]
密度 1.56 g/cm3
熔点 280 °C(553 K)
危险性
GHS危险性符号
《全球化学品统一分类和标签制度》(简称“GHS”)中有害物质的标签图案
GHS提示词 警告
H-术语 H315, H319, H335
P-术语 P261, P264, P264+265, P271, P280, P302+352, P304+340, P305+351+338, P319, P321, P332+317, P337+317, P362+364, P403+233
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Marasinghe, P. A. B.; Gillispie, G. D. Structure of 1,5-dihydroxyanthraquinone: A redetermination. Acta Crystallographica Section C Crystal Structure Communications. 1993, 49 (1): 113–114. Bibcode:1993AcCrC..49..113M. doi:10.1107/s0108270192004542. 
  2. ^ Cai, Yi-Zhong; Mei Sun; Jie Xing; Luo, Qiong; Corke, Harold. Structure–radical scavenging activity relationships of phenolic compounds from traditional Chinese medicinal plants. Life Sciences. 2006, 78 (25): 2872–2888. PMID 16325868. doi:10.1016/j.lfs.2005.11.004. 
  3. ^ Lin, Yue-Jian; Han, Ying-Feng; Jin, Guo-Xin. Synthesis and Structural characterization of half-sandwich iridium macro-metallacycles containing 1,5-dihydroxy-9,10- anthraquinone ligand. Journal of Organometallic Chemistry. 2012,. 708-709: 31–36. doi:10.1016/j.jorganchem.2012.02.014.