1-十六醛
1-十六醛是一种有机化合物，属于醛类，化学式为C16H32O。它可由吡啶氯铬酸盐氧化1-十六烷醇制得。[3]镁-氯化亚锡试剂又可将其还原为醇。[4]它和溴乙酸乙酯在锌、盐酸存在下反应，可以得到3-羟基十八酸乙酯；[5]3,3-二氟-3-溴丙烯和铟可以与之发生相似反应，生成3,3-二氟十九碳-1-烯-4-醇。[6]
| 1-十六醛 | |
|---|---|
| |
| IUPAC名 hexadecanal | |
| 别名 | Hexadecanal; AI3-24252; EINECS 211-111-0; UNII-WQD27655QE |
| 识别 | |
| CAS号 | 629-80-1 
|
| PubChem | 984 |
| ChemSpider | 959 |
| SMILES |
|
| InChI |
|
| InChIKey | NIOYUNMRJMEDGI-UHFFFAOYSA-N |
| EINECS | 211-111-0 |
| ChEBI | 17600 |
| KEGG | C00517 |
| 性质 | |
| 化学式 | C16H32O |
| 摩尔质量 | 240.42 g·mol−1 |
| 熔点 | 34—35 °C（307—308 K）[1] |
| 沸点 | 160—162 °C（433—435 K）（13 torr）[2] |
| 溶解性（水） | 难溶 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ Gordeev, K. Yu.; Serebrennikova, G. A.; Evstigneeva, R. P. Use of anionites in the tetrahydroborate form for obtaining higher liquid aldehydes. Zhurnal Organicheskoi Khimii, 1985. 21 (12): 2615-2616. ISSN 0514-7492
- ^ Enzo Santaniello, Fulvia Milani, Rosangela Casati. Tetrabutylammonium Chlorochromate, A New Mild and Selective Oxidizing Agent. Synthesis. 1983, 1983 (09): 749–751 [2021-11-23]. ISSN 0039-7881. doi:10.1055/s-1983-30500. （原始内容存档于2018-06-07） （英语）.
- ^ Thomas W. Bevan, James Francis-Taylor, Helena Wong, Peter T. Northcote, Joanne E. Harvey. A colourful azulene-based protecting group for carboxylic acids. Tetrahedron. 2018-06, 74 (24): 2942–2955 [2021-11-23]. doi:10.1016/j.tet.2018.04.066 （英语）.
- ^ Manobjyoti Bordoloi, Ram P Sharmat, Vaishali Chakraborty. Magnesium-Tin(II) Chloride Dihydrate: A New System for Chemoselective Reduction of Aldehydes into Alcohols in the Presence of Ketones, Ketalization of Ketones and Dehalogenation of Benzyl Halides. Synthetic Communications. 1999-07, 29 (14): 2501–2506 [2021-11-23]. ISSN 0039-7911. doi:10.1080/00397919908086257 （英语）.
- ^ Jenny, E. F.; Grob, C. A. The synthesis of erythro-dihydrosphingosine from trans-2-octadecenoic acid. Helvetica Chimica Acta, 1953. 36: 1936-1944. ISSN 0018-019X.
- ^ Hikaru Yanai, Haruna Okada, Azusa Sato, Midori Okada, Takeo Taguchi. Copper-free defluorinative alkylation of allylic difluorides through Lewis acid-mediated C–F bond activation. Tetrahedron Letters. 2011-06, 52 (23): 2997–3000 [2021-11-23]. doi:10.1016/j.tetlet.2011.03.148. （原始内容存档于2018-06-25） （英语）.