1-金刚烷硫醇
化合物
1-金刚烷硫醇是一种有机硫化合物，化学式为C10H15SH。它可由1-溴金刚烷、硫脲、氢溴酸和冰乙酸回流反应，再经氢氧化钠水解、盐酸酸化得到；[1]或由1-金刚烷醇和劳森试剂反应制得。[2]它可以被高锰酸钾氧化为二(1-金刚烷基)二硫。[3]
| 1-金刚烷硫醇 | |
|---|---|
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| 识别 | |
| CAS号 | 34301-54-7 
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| SMILES |
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| 性质 | |
| 化学式 | C10H16S |
| 摩尔质量 | 168.3 g·mol−1 |
| 外观 | 白色固体[1] |
| 熔点 | 100-102 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 1.2 Studies on the diastereoselective oxidation of 1-thio-β-D-glucopyranosides: synthesis of the usually less favoured RS sulfoxide as a single diastereoisomer. Organic & Biomolecular Chemistry, 2015. doi:10.1039/C4OB02030H
- ^ S-alkyl Dithiocarbamates Synthesis through Electrochemical Multicomponent Reaction of Thiols, Hydrogen Sulfide, and Isocyanides. J. Org. Chem. 2023, 88, 17, 12311–12318. doi:10.1021/acs.joc.3c01017
- ^ Ground solid permanganate oxidative coupling of thiols into symmetrical/unsymmetrical disulfides: selective and improved process. Journal of Sulfur Chemistry, 2022. 43 (6). doi:10.1080/17415993.2022.2083914