2,5-二羟基-1,4-苯二甲醛

化合物

2,5-二羟基-1,4-苯二甲醛是一种有机化合物,化学式为C8H6O4,它可由2,5-二甲氧基-1,4-苯二甲醛和三溴化硼在无水二氯甲烷中于0 °C反应制得。[3]它和苯胺乙醇中回流反应,可以得到2,5-二(苯亚氨基)-1,4-苯二酚。[4]

2,5-二羟基-1,4-苯二甲醛
识别
CAS号 1951-36-6  checkY
SMILES
 
  • O=Cc1cc(O)c(C=O)cc1O
性质
化学式 C8H6O4
摩尔质量 166.13 g·mol−1
密度 1.515±0.06 g·cm−3[1]
熔点 257—260 °C(530—533 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-12-10].
  2. ^ Cheng-Chu Zeng, James Y. Becker. Anodic Oxidation of Mono- and Disubstituted 1,4-Dimethoxybenzenes. The Journal of Organic Chemistry. 2004-02, 69 (4): 1053–1059 [2020-12-10]. ISSN 0022-3263. doi:10.1021/jo0302253 (英语). 
  3. ^ Qiang Zhu, Xue Wang, Rob Clowes, Peng Cui, Linjiang Chen, Marc A. Little, Andrew I. Cooper. 3D Cage COFs: A Dynamic Three-Dimensional Covalent Organic Framework with High-Connectivity Organic Cage Nodes. Journal of the American Chemical Society. 2020-09-30, 142 (39): 16842–16848 [2020-12-10]. ISSN 0002-7863. doi:10.1021/jacs.0c07732. (原始内容存档于2020-11-06) (英语). 
  4. ^ Manman Mu, Yanwen Wang, Yutian Qin, Xilong Yan, Yang Li, Ligong Chen. Two-Dimensional Imine-Linked Covalent Organic Frameworks as a Platform for Selective Oxidation of Olefins. ACS Applied Materials & Interfaces. 2017-07-12, 9 (27): 22856–22863 [2020-12-10]. ISSN 1944-8244. doi:10.1021/acsami.7b05870 (英语).