2-甲基嘧啶
化合物
2-甲基嘧啶是一种有机化合物,化学式为C5H6N2。它可由2-氯嘧啶和二甲基锌在二氯化[1,2-二(二苯基膦)基乙烷]钯的催化下反应得到。[2]它可以被二氟化银氟化,生成4-氟-2-甲基嘧啶。[3]它可以和高氯酸银形成配合物。[4]
2-甲基嘧啶 | |
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识别 | |
CAS号 | 5053-43-0 ![]() |
性质 | |
化学式 | C5H6N2 |
摩尔质量 | 94.11 g·mol−1 |
熔点 | −4 °C[1] |
沸点 | 138 °C[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-10-23].
- ^ John M. Herbert. Negishi-type coupling of bromoarenes with dimethylzinc. Tetrahedron Letters. 2004-01, 45 (4): 817–819 [2021-10-23]. doi:10.1016/j.tetlet.2003.11.018. (原始内容存档于2018-06-20) (英语).
- ^ Patrick S. Fier, John F. Hartwig. Synthesis and Late-Stage Functionalization of Complex Molecules through C–H Fluorination and Nucleophilic Aromatic Substitution. Journal of the American Chemical Society. 2014-07-16, 136 (28): 10139–10147 [2021-10-23]. ISSN 0002-7863. PMC 4227713 . PMID 24918484. doi:10.1021/ja5049303. (原始内容存档于2021-10-26) (英语).
- ^ Paira, Mrinal Kanti; Dinda, Joydev; Wu, Jian-Sung; Lu, Tian-Huey; Sinha, Chittaranjan. Silver complex of 2-methylpyrimidine. Two dimensional coordination polymer. Journal of the Indian Chemical Society, 2007. 84 (10): 978-982.