2-硝基肉桂醛
2-硝基肉桂醛是一种有机化合物,化学式为C9H7NO3,它是肉桂醛邻位氢被硝基取代的产物。它可由2-硝基苯甲醛和乙醛在碱性条件下反应制得。[2]它催化加氢,可以得到1,2,3,4-四氢喹啉。[3]
2-硝基肉桂醛[1] | |
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IUPAC名 (2E)-3-(2-Nitrophenyl)prop-2-enal | |
识别 | |
CAS号 | 1466-88-2 ![]() |
PubChem | 5367122 |
ChemSpider | 4518729 |
SMILES |
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InChI |
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InChIKey | VMSMELHEXDVEDE-HWKANZROBN |
性质 | |
化学式 | C9H7O3N |
外观 | 浅黄色晶体 |
熔点 | 124-126 °C |
溶解性(水) | 微溶 |
危险性 | |
GHS危险性符号![]() | |
GHS提示词 | 警告 |
H-术语 | H315, H319, H335 |
P-术语 | P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ http://www.21cnlab.com/chemdict/MSDS/62967.html (页面存档备份,存于互联网档案馆) 2-Nitrocinnamaldehyde MSDS
- ^ Rui-Guang Xing, Ya-Nan Li, Qiang Liu, Yi-Feng Han, Xia Wei, Jing Li, Bo Zhou. Selective Reduction of Nitroarenes by a Hantzsch 1,4-Dihydropyridine: A Facile and Efficient Approach to Substituted Quinolines. Synthesis. 2011-07, 2011 (13): 2066–2072 [2022-03-10]. ISSN 0039-7881. doi:10.1055/s-0030-1260609. (原始内容存档于2018-06-07) (英语).
- ^ Francisco G. Cirujano, Antonio Leyva-Pérez, Avelino Corma, Francesc X. Llabrés i Xamena. MOFs as Multifunctional Catalysts: Synthesis of Secondary Arylamines, Quinolines, Pyrroles, and Arylpyrrolidines over Bifunctional MIL-101. ChemCatChem. 2013-02, 5 (2): 538–549 [2022-03-10]. doi:10.1002/cctc.201200878 (英语).