4-叔丁基-1,2-苯二酚
化合物
4-叔丁基-1,2-苯二酚是一种有机化合物,化学式为C10H14O2。它可由邻苯二酚和2-甲基丙烯加热反应制得。[3]它和NBS反应,可以得到3-溴-5-叔丁基-1,2-苯二酚[4];它可以被高碘酸钠氧化为4-叔丁基-3,5-环己二烯-1,2-二酮[5]。它可用作烯烃的阻聚剂和抗氧化剂。[6]
4-tert-Butylcatechol | |
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IUPAC名 4-tert-Butylbenzene-1,2-diol | |
别名 | 4-叔丁基邻苯二酚 对叔丁基邻苯二酚 |
识别 | |
缩写 | TBC |
CAS号 | 98-29-3 ![]() |
PubChem | 7381 |
ChemSpider | 7103 |
SMILES |
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InChI |
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InChIKey | XESZUVZBAMCAEJ-UHFFFAOYAR |
性质 | |
化学式 | C10H14O2 |
摩尔质量 | 166.217 g·mol⁻¹ |
熔点 | 54 °C(327 K)[1] |
沸点 | 285 °C(558 K)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Yasuhiro Kamitori, Masaru Hojo, Ryoichi Masuda, Tatsuo Izumi, Shuichi Tsukamoto. Silica gel as an effective catalyst for the alkylation of phenols and some heterocyclic aromatic compounds. The Journal of Organic Chemistry. 1984-11, 49 (22): 4161–4165 [2020-05-29]. ISSN 0022-3263. doi:10.1021/jo00196a012 (英语).
- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2020-5-17]
- ^ 杨春华, 刘凌波, 臧阳陵,等. 对叔丁基邻苯二酚的合成研究. 精细化工中间体, 2007, 037(003):25-26,62. doi: CNKI:SUN:HNHG.0.2007-03-007
- ^ Kevin Greenaway, Paolo Dambruoso, Alessandro Ferrali, Andrew Hazelwood, Filippo Sladojevich, Darren Dixon. Enantioselective Organocatalytic Aryloxylation of β-Keto Esters. Synthesis. 2011-06, 2011 (12): 1880–1886 [2020-05-29]. ISSN 0039-7881. doi:10.1055/s-0030-1260059. (原始内容存档于2018-06-05) (英语).
- ^ Annika Borrmann, Olumide Fatunsin, Jan Dommerholt, Anika M. Jonker, Dennis W. P. M. Löwik, Jan C. M. van Hest, Floris L. van Delft. Strain-Promoted Oxidation-Controlled Cyclooctyne–1,2-Quinone Cycloaddition (SPOCQ) for Fast and Activatable Protein Conjugation. Bioconjugate Chemistry. 2015-02-18, 26 (2): 257–261 [2020-05-29]. ISSN 1043-1802. doi:10.1021/bc500534d. (原始内容存档于2020-11-21) (英语).
- ^ 对叔丁基邻苯二酚 (页面存档备份,存于互联网档案馆). ChemicalBook. [2020-05-17].