4-氰基吡啶

化合物

4-氰基吡啶是一种有机化合物,化学式为C6H4N2。它可由4-甲基吡啶焦磷酸氧钒的催化下和反应得到。[1]在金属氧化物催化下,它可以水解为异烟酰胺英语Isonicotinamide[2][3]它和叠氮化钠反应,可以得到4-(2H-四唑-5-基)吡啶。[4]

4-氰基吡啶
英文名 4-Pyridinecarbonitrile
识别
CAS号 100-48-1  checkY
性质
化学式 C6H4N2
摩尔质量 104.11 g·mol−1
熔点 79 °C(352 K)
沸点 213.5 °C(487 K)
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Matsuura, I. Vanadyl pyrophosphate as a selective oxidation catalyst. Studies in Surface Science and Catalysis, 1992. 72: 247-254. ISSN 0167-2991.
  2. ^ Claudio Battilocchio, Joel M. Hawkins, Steven V. Ley. Mild and Selective Heterogeneous Catalytic Hydration of Nitriles to Amides by Flowing through Manganese Dioxide. Organic Letters. 2014-02-21, 16 (4): 1060–1063 [2022-01-10]. ISSN 1523-7060. doi:10.1021/ol403591c. (原始内容存档于2022-01-10) (英语). 
  3. ^ Yuvaraj Gangarajula, Buvaneswari Gopal. Investigation of nano NiO, supported and metal ion substituted NiO for selective hydration of aromatic nitriles to amides. Applied Catalysis A: General. 2014-04, 475: 211–217 [2022-01-10]. doi:10.1016/j.apcata.2014.01.036. (原始内容存档于2018-06-30) (英语). 
  4. ^ Leiming Lang, Baojun Li, Wei Liu, Li Jiang, Zheng Xu, Gui Yin. Mesoporous ZnS nanospheres: a high activity heterogeneous catalyst for synthesis of 5-substituted 1H-tetrazoles from nitriles and sodium azide. Chem. Commun. 2010, 46 (3): 448–450 [2022-01-10]. ISSN 1359-7345. doi:10.1039/B912284B (英语).