4-硝基亚苄基丙酮

4-硝基亚苄基丙酮是一种有机化合物,化学式为C10H9NO3。它可由4-硝基苯甲醛丙酮的Claisen-Schmidt缩合反应制得。[1]氯化锌的催化下,它可以被三甲氧基硅烷还原为1-(4-硝基苯基)-1-丁烯。[2]

4-硝基亚苄基丙酮
英文名 4-Nitrobenzylideneacetone
识别
CAS号 3490-37-7  checkY
性质
化学式 C10H9NO3
摩尔质量 191.18 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Song, Yanlei; Wang, Xincheng; Huang, Chongpin; Liang, Fengbing; Yu, Zhichao; Chen, Biaohua. Claisen-Schmidt Condensation Catalyzed by Alkaline Poly(ionic liquid). Youji Huaxue (Chinese Journal of Organic Chemistry). 2013, 33 (8): 1715. ISSN 0253-2786. doi:10.6023/cjoc201301049. 
  2. ^ Jiayun Li, Jiajian Peng, Ying Bai, Lingzhen Chen, Guoqiao Lai. Rapid Selective Defunctionalization of the Carbonyl Group of α,β -Unsaturated Ketones with Trialkoxylsilane/ZnX 2. Phosphorus, Sulfur, and Silicon and the Related Elements. 2011-08-01, 186 (8): 1621–1625 [2021-07-15]. ISSN 1042-6507. doi:10.1080/10426507.2010.536188 (英语).