5,5'-联四唑

5,5'-联四唑是一种有机化合物,化学式为C2H2N8。它可由叠氮化钠三氯化铝存在下反应制得,[1]或由5,5'-联四唑二钠和盐酸反应得到。[2]它和过一硫酸钾乙酸钾反应,可以得到二羟基联四唑。[3]

5,5'-联四唑
识别
CAS号 2783-98-4  checkY
PubChem 137711
SMILES
 
  • N1=NNC(=N1)C2=NN=NN2
性质
化学式 C2H2N8
摩尔质量 138.09 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Turnbull, K., Narsaiah, B., Yadav, J. S., Yakaiah, T., & Lingaiah, B. P. V. (2008). Sodium Azide. Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289x.rs045.pub2
  2. ^ Eulgem, Patrick J.; Klein, Axel; Maggiarosa, Nicola; Naumann, Dieter; Pohl, Roland W. H. New Rare Earth Metal Complexes with Nitrogen‐Rich Ligands: 5,5′‐Bitetrazolate and 1,3‐Bis(tetrazol‐5‐yl)triazenate—On the Borderline between Coordination and the Formation of Salt‐Like Compounds. Chemistry – A European Journal. 2008-04-18, 14 (12): 3727–3736. ISSN 0947-6539. doi:10.1002/chem.200702006. }
  3. ^ Fischer, Niko; Gao, Li; Klapötke, Thomas M.; Stierstorfer, Jörg. Energetic salts of 5,5′-bis(tetrazole-2-oxide) in a comparison to 5,5′-bis(tetrazole-1-oxide) derivatives. Polyhedron. 2013, 51: 201–210. doi:10.1016/j.poly.2012.12.015.