乳酸锂

化合物

乳酸锂是一种化合物,化学式为C3H5LiO3。它可由乳酸碳酸锂反应得到,[1]它可形成正交晶系晶体,空间群P212121[2]它和三光气反应,可以得到乳酸-O-内酐英语Lactic acid O-carboxyanhydride[3]它可用作前驱体制备Li4SiO4[4]、Li4Ti5O12/C[5]等材料。

乳酸锂
别名 2-羟基丙酸锂
识别
CAS号 867-55-0  checkY
PubChem 24867598
SMILES
 
  • [Li+].CC(C(=O)[O-])O
EINECS 212-761-8
性质
化学式 C
3
H
5
LiO
3
摩尔质量 96.01 g·mol⁻¹
外观 晶体
熔点 300 °C(573 K)
溶解性 易溶
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Printsev, M. D.; Vladimirova, N. G.; Maiorova, I. G. Method for obtaining lithium lactate from a crude lactic acid preparation(俄文). Laboratornoe Delo, 1984. 2: 127. ISSN 0023-6748. CODEN LABDAZ.
  2. ^ K. D. Singh, S. C. Jain, T. D. Sakore, A. B. Biswas. Crystal structure of some metal complexes of lactic acid. Zeitschrift für Kristallographie. 1975-10, 141 (5-6): 473–475 [2022-01-18]. ISSN 0044-2968. doi:10.1524/zkri.1975.141.5-6.473. (原始内容存档于2022-01-18) (英语). 页面存档备份,存于互联网档案馆
  3. ^ Roman Nölle, Jan-Patrick Schmiegel, Martin Winter, Tobias Placke. Tailoring Electrolyte Additives with Synergistic Functional Moieties for Silicon Negative Electrode-Based Lithium Ion Batteries: A Case Study on Lactic Acid O -Carboxyanhydride. Chemistry of Materials. 2020-01-14, 32 (1): 173–185 [2022-01-18]. ISSN 0897-4756. doi:10.1021/acs.chemmater.9b03173. (原始内容存档于2022-01-18) (英语). 页面存档备份,存于互联网档案馆
  4. ^ Xinwei Yang, Wenqiang Liu, Jian Sun, Yingchao Hu, Wenyu Wang, Hongqiang Chen, Yang Zhang, Xian Li, Minghou Xu. Preparation of Novel Li 4 SiO 4 Sorbents with Superior Performance at Low CO 2 Concentration. ChemSusChem. 2016-07-07, 9 (13): 1607–1613 [2022-01-18]. doi:10.1002/cssc.201501699 (英语). 
  5. ^ I. A. Stenina, A. N. Sobolev, A. A. Kuz’mina, T. L. Kulova, A. B. Yaroslavtsev. Effect of the Carbon Source on the Electrochemical Properties of Li4Ti5O12/C Composites Prepared by Solid-State Synthesis. Inorganic Materials. 2019-08, 55 (8): 803–809 [2022-01-18]. ISSN 0020-1685. doi:10.1134/S0020168519080156 (英语).