乳酸锂
化合物
乳酸锂是一种化合物,化学式为C3H5LiO3。它可由乳酸和碳酸锂反应得到,[1]它可形成正交晶系晶体,空间群P212121。[2]它和三光气反应,可以得到乳酸-O-内酐。[3]它可用作前驱体制备Li4SiO4[4]、Li4Ti5O12/C[5]等材料。
乳酸锂 | |
---|---|
别名 | 2-羟基丙酸锂 |
识别 | |
CAS号 | 867-55-0 |
PubChem | 24867598 |
SMILES |
|
EINECS | 212-761-8 |
性质 | |
化学式 | C 3H 5LiO 3 |
摩尔质量 | 96.01 g·mol⁻¹ |
外观 | 晶体 |
熔点 | 300 °C(573 K) |
溶解性(水) | 易溶 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Printsev, M. D.; Vladimirova, N. G.; Maiorova, I. G. Method for obtaining lithium lactate from a crude lactic acid preparation(俄文). Laboratornoe Delo, 1984. 2: 127. ISSN 0023-6748. CODEN LABDAZ.
- ^ K. D. Singh, S. C. Jain, T. D. Sakore, A. B. Biswas. Crystal structure of some metal complexes of lactic acid. Zeitschrift für Kristallographie. 1975-10, 141 (5-6): 473–475 [2022-01-18]. ISSN 0044-2968. doi:10.1524/zkri.1975.141.5-6.473. (原始内容存档于2022-01-18) (英语). (页面存档备份,存于互联网档案馆)
- ^ Roman Nölle, Jan-Patrick Schmiegel, Martin Winter, Tobias Placke. Tailoring Electrolyte Additives with Synergistic Functional Moieties for Silicon Negative Electrode-Based Lithium Ion Batteries: A Case Study on Lactic Acid O -Carboxyanhydride. Chemistry of Materials. 2020-01-14, 32 (1): 173–185 [2022-01-18]. ISSN 0897-4756. doi:10.1021/acs.chemmater.9b03173. (原始内容存档于2022-01-18) (英语). (页面存档备份,存于互联网档案馆)
- ^ Xinwei Yang, Wenqiang Liu, Jian Sun, Yingchao Hu, Wenyu Wang, Hongqiang Chen, Yang Zhang, Xian Li, Minghou Xu. Preparation of Novel Li 4 SiO 4 Sorbents with Superior Performance at Low CO 2 Concentration. ChemSusChem. 2016-07-07, 9 (13): 1607–1613 [2022-01-18]. doi:10.1002/cssc.201501699 (英语).
- ^ I. A. Stenina, A. N. Sobolev, A. A. Kuz’mina, T. L. Kulova, A. B. Yaroslavtsev. Effect of the Carbon Source on the Electrochemical Properties of Li4Ti5O12/C Composites Prepared by Solid-State Synthesis. Inorganic Materials. 2019-08, 55 (8): 803–809 [2022-01-18]. ISSN 0020-1685. doi:10.1134/S0020168519080156 (英语).