吡啶-2,6-二甲酸氢锫(III)
吡啶-2,6-二甲酸氢锫(III)是一种配位化合物，化学式为Bk(C7H4NO4)3，或简写为Bk(HDPA)3。有文献对其结构进行理论计算，结果与实验值相符。[1]
| 吡啶-2,6-二甲酸氢锫(III) | |
|---|---|
| |
| 识别 | |
| CAS号 | 1996666-90-0 
|
| 性质 | |
| 化学式 | Bk(C7H4NO4)3 |
| 摩尔质量 | 745.348 g·mol⁻¹ |
| 外观 | 金黄色六边形晶体 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
制备
将三氯化锫和过量的吡啶-2,6-二甲酸在1:1乙醇水溶液中于150°C进行水热反应，可以得到吡啶-2,6-二甲酸氢锫(III)的晶体。[2]
参考文献
- ^ Morgan P. Kelley, Jing Su, Matthew Urban, Morgan Luckey, Enrique R. Batista, Ping Yang, Jenifer C. Shafer. On the Origin of Covalent Bonding in Heavy Actinides. Journal of the American Chemical Society. 2017-07-12, 139 (29): 9901–9908 [2018-12-05]. ISSN 0002-7863. doi:10.1021/jacs.7b03251 （英语）.
- ^ Thomas E. Albrecht-Schmitt, Jenifer Braley, Ping Yang, Paul Kögerler, Manfred Speldrich, Jochen Autschbach, Frédéric Gendron, Laurent Maron, Kenneth Hanson, David E. Hobart, Ashley L. Gray, Lambertus J. van de Burgt, Teresa M. Eaton, Matthew L. Marsh, Shelley M. Van Cleve, Kuan-Wen Chen, Guokui Liu, Alexander Chemey, Matthew J. Polinski, Jamie C. Wang, Matthew Urban, Morgan Luckey, Alexandra A. Arico, Ryan E. Baumbach, Jason A. Johnson, Samantha K. Cary, Mark A. Silver. Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state. Science. 2016-08-26, 353 (6302): aaf3762 [2018-12-05]. ISSN 1095-9203. doi:10.1126/science.aaf3762. （原始内容存档于2020-11-27） （英语）.