吡啶-2,6-二甲酸氫錇(III)

吡啶-2,6-二甲酸氫錇(III)是一種配位化合物,化學式為Bk(C7H4NO4)3,或簡寫為Bk(HDPA)3。有文獻對其結構進行理論計算,結果與實驗值相符。[1]

吡啶-2,6-二甲酸氫錇(III)
識別
CAS號 1996666-90-0  checkY
性質
化學式 Bk(C7H4NO4)3
摩爾質量 745.348 g·mol⁻¹
外觀 金黃色六邊形晶體
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

製備

三氯化錇和過量的吡啶-2,6-二甲酸在1:1乙醇水溶液中於150°C進行水熱反應,可以得到吡啶-2,6-二甲酸氫錇(III)的晶體。[2]

參考文獻

  1. ^ Morgan P. Kelley, Jing Su, Matthew Urban, Morgan Luckey, Enrique R. Batista, Ping Yang, Jenifer C. Shafer. On the Origin of Covalent Bonding in Heavy Actinides. Journal of the American Chemical Society. 2017-07-12, 139 (29): 9901–9908 [2018-12-05]. ISSN 0002-7863. doi:10.1021/jacs.7b03251 (英語). 
  2. ^ Thomas E. Albrecht-Schmitt, Jenifer Braley, Ping Yang, Paul Kögerler, Manfred Speldrich, Jochen Autschbach, Frédéric Gendron, Laurent Maron, Kenneth Hanson, David E. Hobart, Ashley L. Gray, Lambertus J. van de Burgt, Teresa M. Eaton, Matthew L. Marsh, Shelley M. Van Cleve, Kuan-Wen Chen, Guokui Liu, Alexander Chemey, Matthew J. Polinski, Jamie C. Wang, Matthew Urban, Morgan Luckey, Alexandra A. Arico, Ryan E. Baumbach, Jason A. Johnson, Samantha K. Cary, Mark A. Silver. Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state. Science. 2016-08-26, 353 (6302): aaf3762 [2018-12-05]. ISSN 1095-9203. doi:10.1126/science.aaf3762. (原始內容存檔於2020-11-27) (英語).