甲酸苯酯

化合物

甲酸苯酯是一种有机化合物,化学式为C7H6O2。它可由苯酚甲酸N,N'-二环己基碳二亚胺二氯甲烷中反应制得。[2]它和溴苯在钯配合物催化下反应,可以得到苯甲酸苯酯[3]

甲酸苯酯
识别
CAS号 1864-94-4  checkY
性质
化学式 C7H6O2
摩尔质量 122.12 g·mol−1
沸点 93~102 °C(90 mmHg)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Hideyuki Konishi; et al. Mechanistic Insight into Weak Base-Catalyzed Generation of Carbon Monoxide from Phenyl Formate and Its Application to Catalytic Carbonylation at Room Temperature without Use of External Carbon Monoxide Gas. Advanced Synthesis & Catalysis. 2017. doi:10.1002/adsc.201700751.
  2. ^ Huang, Jianing; et al. A convenient synthesis of aryl formates. Journal of Chemical Research, Synopses (1991), (10), 292-293
  3. ^ Ueda, Tsuyoshi; et al. Palladium-Catalyzed Carbonylation of Aryl, Alkenyl, and Allyl Halides with Phenyl Formate. Organic Letters (2012), 14(12), 3100-3103