甲酸苯酯

化合物

甲酸苯酯是一種有機化合物,化學式為C7H6O2。它可由苯酚甲酸N,N'-二環己基碳二亞胺二氯甲烷中反應製得。[2]它和溴苯在鈀配合物催化下反應,可以得到苯甲酸苯酯[3]

甲酸苯酯
識別
CAS號 1864-94-4  checkY
性質
化學式 C7H6O2
摩爾質量 122.12 g·mol−1
沸點 93~102 °C(90 mmHg)[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ Hideyuki Konishi; et al. Mechanistic Insight into Weak Base-Catalyzed Generation of Carbon Monoxide from Phenyl Formate and Its Application to Catalytic Carbonylation at Room Temperature without Use of External Carbon Monoxide Gas. Advanced Synthesis & Catalysis. 2017. doi:10.1002/adsc.201700751.
  2. ^ Huang, Jianing; et al. A convenient synthesis of aryl formates. Journal of Chemical Research, Synopses (1991), (10), 292-293
  3. ^ Ueda, Tsuyoshi; et al. Palladium-Catalyzed Carbonylation of Aryl, Alkenyl, and Allyl Halides with Phenyl Formate. Organic Letters (2012), 14(12), 3100-3103