甲酸苯酯
化合物
甲酸苯酯是一種有機化合物,化學式為C7H6O2。它可由苯酚、甲酸和N,N'-二環己基碳二亞胺在二氯甲烷中反應製得。[2]它和溴苯在鈀配合物催化下反應,可以得到苯甲酸苯酯。[3]
甲酸苯酯 | |
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識別 | |
CAS號 | 1864-94-4 |
性質 | |
化學式 | C7H6O2 |
摩爾質量 | 122.12 g·mol−1 |
沸點 | 93~102 °C(90 mmHg)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
- ^ Hideyuki Konishi; et al. Mechanistic Insight into Weak Base-Catalyzed Generation of Carbon Monoxide from Phenyl Formate and Its Application to Catalytic Carbonylation at Room Temperature without Use of External Carbon Monoxide Gas. Advanced Synthesis & Catalysis. 2017. doi:10.1002/adsc.201700751.
- ^ Huang, Jianing; et al. A convenient synthesis of aryl formates. Journal of Chemical Research, Synopses (1991), (10), 292-293
- ^ Ueda, Tsuyoshi; et al. Palladium-Catalyzed Carbonylation of Aryl, Alkenyl, and Allyl Halides with Phenyl Formate. Organic Letters (2012), 14(12), 3100-3103