4-硝基亚苄基丙二腈

化合物

4-硝基亚苄基丙二腈是一种有机化合物,化学式为C10H5N3O2。它可由4-硝基苯甲醛丙二腈的Knoevenagel缩合反应制得。[2]它和次氯酸钙反应,可以得到2,2-二氰基-3-(4-硝基苯基)环氧乙烷。[3]

4-硝基亚苄基丙二腈
别名 1-(2,2-二氰乙烯基)-4-硝基苯
2-[(4-硝基苯基)亚甲基]丙二腈
识别
CAS号 2700-23-4  checkY
性质
化学式 C10H5N3O2
摩尔质量 199.17 g·mol⁻¹
熔点 160 °C(433 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Saeed Balalaie, Morteza Bararjanian, Shohreh Hekmat, Peyman Salehi. Novel, Efficient, and Green Procedure for the Knoevenagel Condensation Catalyzed by Diammonium Hydrogen Phosphate in Water. Synthetic Communications. 2006-12, 36 (24): 3703–3711 [2021-05-17]. ISSN 0039-7911. doi:10.1080/10916460600946113 (英语). 
  2. ^ Bhaskar Sarmah, Biswarup Satpati, Rajendra Srivastava. Highly efficient and recyclable basic mesoporous zeolite catalyzed condensation, hydroxylation, and cycloaddition reactions. Journal of Colloid and Interface Science. 2017-05, 493: 307–316 [2021-05-17]. doi:10.1016/j.jcis.2017.01.039 (英语). 
  3. ^ F. Mirhashemi, M.A. Amrollahi. Epoxidation of vinyl cyanides by calcium hypochlorite under catalyst- and solvent-free conditions. Tetrahedron Letters. 2018-07, 59 (27): 2661–2663 [2021-05-17]. doi:10.1016/j.tetlet.2018.05.077 (英语).