4-硝基亚苄基丙二腈
化合物
4-硝基亚苄基丙二腈是一种有机化合物,化学式为C10H5N3O2。它可由4-硝基苯甲醛和丙二腈的Knoevenagel缩合反应制得。[2]它和次氯酸钙反应,可以得到2,2-二氰基-3-(4-硝基苯基)环氧乙烷。[3]
4-硝基亚苄基丙二腈 | |
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别名 | 1-(2,2-二氰乙烯基)-4-硝基苯 2-[(4-硝基苯基)亚甲基]丙二腈 |
识别 | |
CAS号 | 2700-23-4 |
性质 | |
化学式 | C10H5N3O2 |
摩尔质量 | 199.17 g·mol⁻¹ |
熔点 | 160 °C(433 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Saeed Balalaie, Morteza Bararjanian, Shohreh Hekmat, Peyman Salehi. Novel, Efficient, and Green Procedure for the Knoevenagel Condensation Catalyzed by Diammonium Hydrogen Phosphate in Water. Synthetic Communications. 2006-12, 36 (24): 3703–3711 [2021-05-17]. ISSN 0039-7911. doi:10.1080/10916460600946113 (英语).
- ^ Bhaskar Sarmah, Biswarup Satpati, Rajendra Srivastava. Highly efficient and recyclable basic mesoporous zeolite catalyzed condensation, hydroxylation, and cycloaddition reactions. Journal of Colloid and Interface Science. 2017-05, 493: 307–316 [2021-05-17]. doi:10.1016/j.jcis.2017.01.039 (英语).
- ^ F. Mirhashemi, M.A. Amrollahi. Epoxidation of vinyl cyanides by calcium hypochlorite under catalyst- and solvent-free conditions. Tetrahedron Letters. 2018-07, 59 (27): 2661–2663 [2021-05-17]. doi:10.1016/j.tetlet.2018.05.077 (英语).