MIL-53
MIL-53是一种金属有机框架材料,名称中字母缩写MIL为Matériaux de l′Institut Lavoisier,它由圣康丁昂伊夫利纳-凡尔赛大学拉瓦锡研究所的Gérard Férey组所合成。[1]目前已知其它三价金属的类似物,如Al[2]、Fe[3]等。不同种类的MIL-53材料按下述区分:MIL-53as(as = as synthesized(合成原态),使用了对苯二甲酸)、MIL-53lt(lt = low temperature(低温),低温改性)和MIL-53ht(ht = high temperature(高温),高温改性)。
MIL-53 | |
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别名 | MIL-53(Cr) |
识别 | |
缩写 | MIL-53(Cr) |
CAS号 | 442912-79-0(无水) ![]() 477890-83-8(一水合物) ![]() 477890-84-9(一DMF合物) ![]() |
性质 | |
化学式 | C8H5CrO5 |
外观 | 固体 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Serre, Christian; Millange, Franck; Thouvenot, Christelle; Noguès, Marc; Marsolier, Gérard; Louër, Daniel; Férey, Gérard. Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or Cr III (OH)·{O 2 C−C 6 H 4 −CO 2 }·{HO 2 C−C 6 H 4 −CO 2 H} x ·H 2 O y. Journal of the American Chemical Society. 2002-11-01, 124 (45). ISSN 0002-7863. doi:10.1021/ja0276974 (英语).
- ^ Loiseau, Thierry; Serre, Christian; Huguenard, Clarisse; Fink, Gerhard; Taulelle, Francis; Henry, Marc; Bataille, Thierry; Férey, Gérard. A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration. Chemistry - A European Journal. 2004-03-19, 10 (6). ISSN 0947-6539. doi:10.1002/chem.200305413 (英语).
- ^ Horcajada, Patricia; Serre, Christian; Maurin, Guillaume; Ramsahye, Naseem A.; Balas, Francisco; Vallet-Regí, María; Sebban, Muriel; Taulelle, Francis; Férey, Gérard. Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery. Journal of the American Chemical Society. 2008-05-01, 130 (21) [2022-10-01]. ISSN 0002-7863. doi:10.1021/ja710973k. (原始内容存档于2022-10-06) (英语).
参见
- 金属有机框架材料(MOF)