2-甲基十二烷
化合物
2-甲基十二烷是一种有机化合物，化学式为C13H28，它是十三烷的同分异构体之一。它可由1-溴癸烷和二异丙基锌的反应[3]、癸基溴化镁和2-溴丙烷的反应[4]或1-十二烯和三甲基铝的反应[5]制备。
| 2-甲基十二烷 | |
|---|---|
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| 识别 | |
| CAS号 | 1560-97-0 
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| PubChem | 15270 |
| SMILES |
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| 性质 | |
| 化学式 | C13H28 |
| 摩尔质量 | 184.36 g·mol−1 |
| 密度 | 0.754 g·cm−3（20 °C）[1] |
| 沸点 | 103—104 °C（376—377 K）（10.5 Torr）[1] 227.7±3.0 °C（760 Torr）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 Bashkirov, A. N.; Shaikhutdinov, E. M.; Gilyarovskaya, L. A. Oxidation of monomethyl-substituted paraffin hydrocarbons in the liquid phase in the presence of boric acid. Doklady Akademii Nauk SSSR, 1963. 148. 1309-1311. ISSN: 0002-3264.
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-06-11].
- ^ Jun Terao, Hirohisa Todo, Hideyuki Watanabe, Aki Ikumi, Nobuaki Kambe. Nickel-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Organozinc and Grignard Reagents with 1,3,8,10-Tetraenes as Additives. Angewandte Chemie International Edition. 2004-11-19, 43 (45): 6180–6182 [2020-06-19]. ISSN 1433-7851. doi:10.1002/anie.200460246 （英语）.
- ^ Gérard Cahiez, Christophe Chaboche, Christophe Duplais, Arianna Giulliani, Alban Moyeux. Cobalt‐Catalyzed Cross‐Coupling Reaction between Functionalized Primary and Secondary Alkyl Halides and Aliphatic Grignard Reagents. Advanced Synthesis & Catalysis. 2008-07-07, 350 (10): 1484–1488 [2020-06-19]. doi:10.1002/adsc.200800166 （英语）.
- ^ Stefan Mark, Nikola Gaidzik, Sven Doye, Markus Enders. Organochromium complexes as catalysts for the carboalumination of unactivated terminal olefins. Dalton Transactions. 2009, (25): 4875 [2020-06-19]. ISSN 1477-9226. doi:10.1039/b902609f （英语）.