二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑

二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑是一種配位化合物,化學式為PtCl2P2C12H24N6。它可由四氯合鉑(II)酸鉀1,3,5-三氮雜-7-磷雜金剛烷(PTA)在乙醇中反應製得,[1],或通過PtCl2(COD)(COD=1,5-環辛二烯)和PTA反應得到。[2]它在0.1 mol/L的鹽酸溶液中可以結晶出無色的cis-[PtCl2(PTAH)2]Cl2晶體。[1]它的配位氯可以被含硫配體取代。[3]

二氯化二(1,3,5-三氮雜-7-磷雜金剛烷)合鉑
識別
CAS號 194346-40-2  checkY
SMILES
 
  • [Cl-][Pt+2]([Cl-])([P]12CN3CN(CN(C3)C1)C2)[P]45CN6CN(CN(C6)C4)C5
性質
化學式 H24Cl2N6P2Pt
摩爾質量 436.17 g·mol−1
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ 1.0 1.1 Donald J. Darensbourg; et al. Water-Soluble Organometallic Compounds. 6.1 Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals. Inorg. Chem. 1997, 36, 19, 4218–4226. doi:10.1021/ic970238x.
  2. ^ Don A. Krogstad; et al. Intramolecular hydroamination of alkynylamines in aqueous media catalyzed by platinum(II) 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry Communications, 2005. 8 (1): 65-69. doi:10.1016/j.inoche.2004.11.006.
  3. ^ Elena Guerrero; et al. trans-Thionate Derivatives of Pt(II) and Pd(II) with Water-Soluble Phosphane PTA and DAPTA Ligands: Antiproliferative Activity against Human Ovarian Cancer Cell Lines. Inorg. Chem. 2013, 52, 11, 6635–6647. doi:10.1021/ic4006746.