PCN-224
PCN-224是鋯和5,10,15,20-四(4-羧基苯基)卟啉（TCPP）形成的金屬有機框架（MOF）之一，其結構可以表示為[Zr6O4(OH)4][TCPP]1.5，其無序變體表示為dPCN-224。[2]它可由四氯化鋯、TCPP和苯甲酸在DMF中反應得到。[1]它的理論表面積為2985 m2/g。[3]
| PCN-224 | |
|---|---|
| 識別 | |
| CAS號 | 1476810-88-4 
|
| 性質 | |
| 化學式 | C144H112N12O64Zr15 |
| 摩爾質量 | 4402.83 g·mol−1 |
| 外觀 | 暗紫色晶體[1] 紫色透明晶體（dPCN-224）[2] |
| 密度 | 0.517 g/cm3（100 K，dPCN-224）[2] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
- ^ 1.0 1.1 Dawei Feng, Wan-Chun Chung, Zhangwen Wei, Zhi-Yuan Gu, Hai-Long Jiang, Ying-Pin Chen, Donald J. Darensbourg, and Hong-Cai Zhou. Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination. J. Am. Chem. Soc. 2013, 135, 45, 17105–17110. doi:10.1021/ja408084j.
- ^ 2.0 2.1 2.2 2.3 Charlotte Koschnick, Robert Stäglich, Tanja Scholz, Maxwell W. Terban, Alberto von Mankowski, Gökcen Savasci, Florian Binder, Alexander Schökel, Martin Etter, Jürgen Nuss, Renée Siegel, Luzia S. Germann, Christian Ochsenfeld, Robert E. Dinnebier, Jürgen Senker & Bettina V. Lotsch. Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221. Nat Commun 12, 3099 (2021). doi:10.1038/s41467-021-23348-w
- ^ Understanding the structure-dependent adsorption behavior of four zirconium-based porphyrinic MOFs for the removal of pharmaceuticals. Microporous and Mesoporous Materials. 2024. doi:10.1016/j.micromeso.2023.112827.