1,4-二氫吡啶

化合物

1,4-二氫吡啶(英語:1,4-Dihydropyridine,縮寫DHP)是一種不穩定的有機化合物,化學式為C5H7N,其零點振動能為0.1125 Ha[3]。它可由1-三甲基矽基-1,4-二氫吡啶和甲醇反應[4],或吡啶氫化鋁鋰反應[5]得到,後者會同時產生其它二氫吡啶的異構體。

1,4-二氫吡啶
Skeletal formula of dihydropyridine
Ball-and-stick model of the dihydropyridine molecule
系統名
1,4-Dihydropyridine[1]
識別
CAS號 3337-17-5  checkY
PubChem 104822
ChemSpider 94619
SMILES
 
  • C1C=CNC=C1
MeSH 1,4-dihydropyridine
性質
化學式 C
5
H
7
N
摩爾質量 81.1158 g mol−1 g·mol⁻¹
密度 0.910±0.06 g·cm−3[2]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ 1,4-dihydropyridine - Compound Summary. Pubchem Compound. USA: National Center for Biotechnology Information. Identification and Related Records. 27 March 2005 [1 November 2011]. (原始內容存檔於2012-10-11). 
  2. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-11-14]
  3. ^ Lan-Fen Wang, Hong-Yu Zhang, Ling Kong, Zhi-Wei Chen, Jian-Guo Shi. DFT Calculations Indicate that 1,4-Dihydropyridine Is a Promising Lead Antioxidant. Helvetica Chimica Acta. 2004-06, 87 (6): 1515–1521 [2019-11-14]. ISSN 0018-019X. doi:10.1002/hlca.200490138 (英語). 
  4. ^ Newell C. Cook, James E. Lyons. 1,4-Dihydropyridine. Journal of the American Chemical Society. 1965-07, 87 (14): 3283–3284 [2019-11-14]. ISSN 0002-7863. doi:10.1021/ja01092a074 (英語). 
  5. ^ Arthur J. Birch, Edouard A. Karakhanov. Preparation of some N-substituted 1,4-dihydropyridines by metal–ammonia reactions. J. Chem. Soc., Chem. Commun. 1975, (12): 480–481 [2019-11-14]. ISSN 0022-4936. doi:10.1039/C39750000480 (英語). 

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