4-硝基碘苯
化合物
4-硝基碘苯是一種有機化合物,化學式為C6H4INO2。它可由4-硝基苯胺和二氧化氮、碘化鈉在乙腈中反應得到。[2]在Pd@CeO2的催化下,它和亞鐵氰酸鉀反應,可以得到4-硝基苯甲腈。[3]在銅催化下,它和氫氧化鈉反應,可以得到4-硝基苯酚。[4]
4-硝基碘苯 | |
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識別 | |
CAS號 | 636-98-6 ![]() |
性質 | |
化學式 | C6H4INO2 |
摩爾質量 | 249.01 g·mol−1 |
熔點 | 174 °C(447 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
- ^ Felix, Guy; Dunogues, Jacques; Calas, Raymond. Regiospecific synthesis of disubstituted benzene derivatives(德文). Angewandte Chemie, 1979. 91 (5): 430-432.
- ^ Hitomi Suzuki, Nobuaki Nonoyama. Nitrogen dioxide - sodium iodide as an efficient reagent for the one-pot conversion of aryl amines to aryl iodides under nonaqueous conditions. Tetrahedron Letters. 1998-06, 39 (25): 4533–4536 [2021-11-24]. doi:10.1016/S0040-4039(98)00824-7. (原始內容存檔於2018-06-11) (英語).
- ^ Shengyu Wang, Jianqiang Wang, Junyi Pan, Cheng Liu, Xubin Gong, Cheng Guo. Pd@CeO 2 ‐catalyzed cyanation of aryl iodides with K 4 Fe(CN) 6 ·3H 2 O under visible light irradiation. Applied Organometallic Chemistry. 2021-03, 35 (3) [2021-11-24]. ISSN 0268-2605. doi:10.1002/aoc.6135. (原始內容存檔於2021-11-24) (英語).
- ^ Leiduan Hao, Anika Auni, Guodong Ding, Xiaoyu Li, Haiping Xu, Tao Li, Qiang Zhang. Selective hydroxylation of aryl iodides to produce phenols under mild conditions using a supported copper catalyst. RSC Advances. 2021, 11 (41): 25348–25353 [2021-11-24]. ISSN 2046-2069. doi:10.1039/D1RA04112F (英語).