1-碘萘
化合物
1-碘萘是一种有机化合物,化学式为C10H7I。它可由1-溴萘和碘化钠在二氧六环中反应制得,[2]或通过萘和N-碘代丁二酰亚胺在1,1,1,3,3,3-六氟-2-丙醇中的反应得到,反应会生成少量的2-碘代副产物。[3]它和苯硼酸在磷酸钾和催化剂的存在下发生偶联反应,可以得到1-苯基萘。[4]它和氰化钾反应,碘被氰基取代,得到1-萘甲腈。[5]
1-碘萘 | |
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别名 | α-碘萘 |
识别 | |
CAS号 | 90-14-2 |
InChI |
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性质 | |
化学式 | C10H7I |
摩尔质量 | 254.07 g·mol−1 |
熔点 | 4.2 °C(277.3 K)[1] |
沸点 | 302 °C(575 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ 跳转到: 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-01-08].
- ^ Dominik Urselmann, Dragutin Antovic, Thomas J J Müller. Pseudo five-component synthesis of 2,5-di(hetero)arylthiophenes via a one-pot Sonogashira–Glaser cyclization sequence. Beilstein Journal of Organic Chemistry. 2011-11-04, 7: 1499–1503 [2021-01-08]. ISSN 1860-5397. doi:10.3762/bjoc.7.174. (原始内容存档于2020-08-12) (英语).
- ^ Ren-Jin Tang, Thierry Milcent, Benoit Crousse. Regioselective Halogenation of Arenes and Heterocycles in Hexafluoroisopropanol. The Journal of Organic Chemistry. 2018-01-19, 83 (2): 930–938 [2021-01-08]. ISSN 0022-3263. doi:10.1021/acs.joc.7b02920. (原始内容存档于2019-10-03) (英语).
- ^ Stephen D. Ramgren, Liana Hie, Yuxuan Ye, Neil K. Garg. Nickel-Catalyzed Suzuki–Miyaura Couplings in Green Solvents. Organic Letters. 2013-08-02, 15 (15): 3950–3953 [2021-01-08]. ISSN 1523-7060. doi:10.1021/ol401727y (英语).
- ^ Benjamin A. Anderson, Edward C. Bell, Francis O. Ginah, Nancy K. Harn, Lisa M. Pagh, James P. Wepsiec. Cooperative Catalyst Effects in Palladium-Mediated Cyanation Reactions of Aryl Halides and Triflates. The Journal of Organic Chemistry. 1998-11, 63 (23): 8224–8228 [2021-01-08]. ISSN 0022-3263. doi:10.1021/jo9808674 (英语).