三(4-甲苯基)均三嗪
化合物
三(4-甲苯基)均三嗪是一种有机化合物，化学式为C24H21N3。它可由三聚氯氰和干甲苯在三氯化铝催化下于60 °C反应得到；[1]或由4-甲基苯甲腈在己胺和碘化亚钐催化下三聚得到。[3]它在硫酸、乙酸及乙酸酐体系中可以被三氧化铬氧化为三(4-羧基苯基)均三嗪。[1]它和硝硫混酸在80 °C反应，可以得到三(4-甲基-3,5-二硝基苯基)均三嗪。[4]
| 三(4-甲苯基)均三嗪 | |
|---|---|
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| 识别 | |
| CAS号 | 6726-45-0 
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| SMILES |
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| 性质 | |
| 化学式 | C24H21N3 |
| 摩尔质量 | 351.44 g·mol−1 |
| 外观 | 白色针状晶体[1] |
| 熔点 | 284—286 °C（557—559 K）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 1.2 Jihye Park; Dawei Feng; Hong-Cai Zhou. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores. J. Am. Chem. Soc. 2015, 137, 4, 1663–1672. doi:10.1021/ja5123528.
- ^ John H. Forsberg; Vincent T. Spaziano; Stephen P. Klump; Kathleen M. Sanders. Lanthanide(III) ion catalyzed reaction of ammonia and nitriles: Synthesis of 2,4,6-trisubstituted-s-triazines. Journal of Heterocyclic Chemistry, 1988. 25 (3): 767-770. doi:10.1002/jhet.5570250312.
- ^ Daofeng Sun; Shengqian Ma; Yanxiong Ke; Tracy M Peterson; Hong-Cai Zhou. Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability. Chem. Commun., 2005, 2663-2665. doi:10.1039/B502007G.
- ^ Yu Gong; Shaofeng Huang; Zepeng Lei; Lacey Wayment; Hongxuan Chen; Wei Zhang. Double-Walled Covalent Organic Frameworks with High Stability. Chemistry - A European Journal (2023), 29 (63), e202302135. doi:10.1002/chem.202302135.