六溴合錸(IV)酸鉀
化合物
六溴合錸(IV)酸鉀是一種配位化合物,化學式為K2ReBr6。它可由高錸酸鉀在濃氫溴酸中被還原劑(如碘離子、亞鉻離子、二氧化硫、肼、甲醛、次磷酸等)還原得到。[1]
Potassium hexabromorhenate | |
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IUPAC名 dipotassium; hexabromo rhenium(2-) | |
識別 | |
CAS號 | 16903-70-1 |
PubChem | 71310035 |
ChemSpider | 4907648 |
SMILES |
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性質 | |
化學式 | Br6K2Re |
摩爾質量 | 743.83 g·mol−1 |
外觀 | 暗紅色晶體 |
密度 | 4.34 g/cm3 |
溶解性(水) | 反應 |
危險性 | |
GHS提示詞 | 警告 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
反應
參考文獻
- ^ Watt, G. W., Thompson, R. J., & Gibbons, J. M. (2007). Potassium Hexachlororhenate(IV) and Potassium Hexabromorhenate(IV). Inorganic Syntheses, 189–192. doi:10.1002/9780470132388.ch51
- ^ Freni, M., & Romiti, P. (1975). New isocyanide complexes of rhenium. Journal of Organometallic Chemistry, 87 (2), 241–245. doi:10.1016/s0022-328x(00)91289-0
- ^ Cameron, C; Wigley, D; Wild, R; Wood, T & Walton, R. (1983). The reactions of K2ReX6 (X = Br OR I) and Re3X9 (X = Cl, Br OR I) with alkyl and aryl isocyanides. Journal of Organometallic Chemistry, 255(3), 345–358. doi:10.1016/s0022-328x(00)99328-8
- ^ Nikita A. Korobeynikov; et al. Halogen-rich halorhenates(IV): (Me4N)2{[ReX6](X2)} (X = Cl, Br). Polyhedron, 2022. 221. 115876. doi:10.1007/BF02741603.
延伸閱讀
- Gubanov, A. I., Korenev, S. V., Gromilov, S. A., Baidina, I. A., & Venediktov, A. B. (2000). Syntheses and X-ray studies of the complexes [M(NH3)4][M′X6] (M = Pt, Pd; M′ = Re, Os; X = Cl, Br). Journal of Structural Chemistry, 41(2), 340–343. doi:10.1007/bf02741603.