癸五炔
癸五炔是一種有機化合物，化學式為C10H2。它可由碳化鈣和含Cu+/Cu2+的氯化銨溶液反應製得，該反應還會生成己三炔和辛四炔等多炔副產物。[1]它可以通過與銀氨溶液反應來提純。[2]它在紫外線[3]或γ射線[4]下可以發生分解。它可以和碘形成分子配合物。[5]
| 癸五炔 | |
|---|---|
| 識別 | |
| CAS號 | 32597-32-3 
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| SMILES |
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| 性質 | |
| 化學式 | C10H2 |
| 摩爾質量 | 122.12 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
- ^ (a) Franco Cataldo. The simplest approach to prepare solutions of polyynes in hydrocarbons. Tetrahedron Letters, 2005. 46 (21): 3665-3667. doi:10.1016/j.tetlet.2005.03.160; (b) Franco Cataldo. A method for synthesizing polyynes in solution. Carbon, 2005. 43 (13): 2792-2800. doi:10.1016/j.carbon.2005.05.024.
- ^ Liang Fang; et al. Purification of polyynes via carbides. Carbon, 2021. 179. 28-32. doi:10.1016/j.carbon.2021.04.032.
- ^ Cataldo, Franco; Strazzulla, Giovanni; Iglesias-Groth, Susana (2008). UV photolysis of polyynes at λ=254 nm and at λ>222 nm. International Journal of Astrobiology, 7(2). doi:10.1017/S147355040800414X
- ^ Cataldo, Franco; Ursini, Ornella; Angelini, Giancarlo; Strazzulla, Giovanni (2008). Polyynes Decomposition with γ Radiation. Fullerenes, Nanotubes and Carbon Nanostructures, 16(4), 272–281.doi:10.1080/15363830802171859
- ^ Wada, Yoriko; et al. Spectroscopic characterization of a series of polyyne-iodine molecular complexes H(C≡C)nH(I6) of n = 5-9. Chemical Physics Letters (2012), 541, 54-59. doi:10.1016/j.cplett.2012.05.035