芝麻菜叶千里光碱

芝麻菜叶千里光碱是一种大环内酯类有机物,化学式为C18H23NO6。它存在于新疆千里光[1]抱茎天芥菜英语Heliotropium amplexicaule[2]等植物中。它在水中可以被高碘酸四氧化锇的混合物氧化。[3]

芝麻菜叶千里光碱
英文名 Erucifoline
识别
CAS号 40158-95-0  checkY
SMILES
 
  • C(O)[C@]12[C@@](C)(O1)C(=O)OCC=3[C@@]4([C@](OC(=O)/C(=C\C)/C2)(CCN4CC3)[H])[H]
性质
化学式 C18H23NO6
摩尔质量 349.38 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Pieter B. Pelser; et al. Frequent gain and loss of pyrrolizidine alkaloids in the evolution of Senecio section Jacobaea (Asteraceae). Phytochemistry, 2005. 66 (11). 1285-1295. doi:10.1016/j.phytochem.2005.04.015.
  2. ^ Matheus Carpinelli de Jesus; Natasha L. Hungerford; Steve J. Carter; Shalona R. Anuj; Joanne T. Blanchfield; James J. De Voss; Mary T. Fletcher. Pyrrolizidine Alkaloids of Blue Heliotrope (Heliotropium amplexicaule) and Their Presence in Australian Honey. J. Agric. Food Chem. 2019, 67, 28, 7995–8006. doi:10.1021/acs.jafc.9b02136.
  3. ^ Sedmera, P.; Klásek, A.; Duffield, A. M.; Šantavý, F. (1972). Pyrrolizidine alkaloids. XIX. Structure of the alkaloid erucifoline. Collection of Czechoslovak Chemical Communications, 37(12), 4112–4119. doi:10.1135/cccc19724112.