肉桂酰氯

化合物

肉桂酰氯是一种有机化合物,化学式为C9H7ClO。它可由肉桂酸氯化亚砜回流反应制得。[2]

肉桂酰氯
识别
CAS号 102-92-1  checkY
17082-09-6(trans)  checkY
59015-50-8(cis)  checkY
性质
化学式 C9H7ClO
摩尔质量 166.6 g·mol−1
熔点 36 °C[1]
沸点 257 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

乙腈中,它可以被/三丁基膦还原为肉桂醛[3]催化下、三乙胺存在下,它和苯乙醛反应,可以得到1,5-二苯基-1-戊烯-4-炔-3-酮。[4]

参考文献

  1. ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2023-03-25].
  2. ^ Gergely Varga, Tibor Docsa, Pál Gergely, László Juhász, László Somsák. Synthesis of tartaric acid analogues of FR258900 and their evaluation as glycogen phosphorylase inhibitors. Bioorganic & Medicinal Chemistry Letters. 2013-03, 23 (6): 1789–1792 [2023-03-25]. doi:10.1016/j.bmcl.2013.01.042. (原始内容存档于2020-06-09) (英语). 
  3. ^ Xueshun Jia, Xiaotao Liu, Jian Li, Peichao Zhao, Yongmin Zhang. A general and efficient reduction of acyl chlorides to aldehydes by Sm(0)/Bu3P. Tetrahedron Letters. 2007-02, 48 (6): 971–974 [2023-03-25]. doi:10.1016/j.tetlet.2006.12.014. (原始内容存档于2019-04-03) (英语). 
  4. ^ Subhankar Santra, Priyadarshi Ranjan, Parthasarathi Bera, Prasenjit Ghosh, Swadhin K. Mandal. Anchored palladium nanoparticles onto single walled carbon nanotubes: Efficient recyclable catalyst for N-containing heterocycles. RSC Advances. 2012, 2 (19): 7523 [2023-03-25]. ISSN 2046-2069. doi:10.1039/c2ra20281f (英语).