肉桂酰氯
化合物
肉桂酰氯是一種有機化合物,化學式為C9H7ClO。它可由肉桂酸和氯化亞碸回流反應製得。[2]
肉桂酰氯 | |
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識別 | |
CAS號 | 102-92-1 17082-09-6(trans) 59015-50-8(cis) |
性質 | |
化學式 | C9H7ClO |
摩爾質量 | 166.6 g·mol−1 |
熔點 | 36 °C[1] |
沸點 | 257 °C[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
在乙腈中,它可以被釤/三丁基膦還原為肉桂醛。[3]在鈀催化下、三乙胺存在下,它和苯乙醛反應,可以得到1,5-二苯基-1-戊烯-4-炔-3-酮。[4]
參考文獻
- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2023-03-25].
- ^ Gergely Varga, Tibor Docsa, Pál Gergely, László Juhász, László Somsák. Synthesis of tartaric acid analogues of FR258900 and their evaluation as glycogen phosphorylase inhibitors. Bioorganic & Medicinal Chemistry Letters. 2013-03, 23 (6): 1789–1792 [2023-03-25]. doi:10.1016/j.bmcl.2013.01.042. (原始內容存檔於2020-06-09) (英語).
- ^ Xueshun Jia, Xiaotao Liu, Jian Li, Peichao Zhao, Yongmin Zhang. A general and efficient reduction of acyl chlorides to aldehydes by Sm(0)/Bu3P. Tetrahedron Letters. 2007-02, 48 (6): 971–974 [2023-03-25]. doi:10.1016/j.tetlet.2006.12.014. (原始內容存檔於2019-04-03) (英語).
- ^ Subhankar Santra, Priyadarshi Ranjan, Parthasarathi Bera, Prasenjit Ghosh, Swadhin K. Mandal. Anchored palladium nanoparticles onto single walled carbon nanotubes: Efficient recyclable catalyst for N-containing heterocycles. RSC Advances. 2012, 2 (19): 7523 [2023-03-25]. ISSN 2046-2069. doi:10.1039/c2ra20281f (英語).