光子上轉換
光子上轉換(英語:Photon upconversion)是吸收較長波長的兩個或多個光子,激發出較短波長的光的過程。[1]它是反斯托克型的發光,這種類型的發光的例子就是將紅外光轉化為可見光。[2][3][4][5][6]具有這一發光特性的材料被稱作上轉換發光材料,它通常含有d區或f區的元素。如Ln3+、Ti2+、Ni2+、Mo3+、Re4+、Os4+等。
![](http://images.weserv.nl/?url=//upload.wikimedia.org/wikipedia/commons/thumb/b/bb/Upconversion_Fluorescence_-_Optical_fiber_that_contains_infrared_light_shines_with_a_blue_color_in_the_dark_-_Laser_Physics_Lab_-_NTNU-NT.jpg/200px-Upconversion_Fluorescence_-_Optical_fiber_that_contains_infrared_light_shines_with_a_blue_color_in_the_dark_-_Laser_Physics_Lab_-_NTNU-NT.jpg)
參考文獻
- ^ Zhou, B.; et al. Controlling Upconversion Nanocrystals for Emerging Applications. Nature Nanotechnology: 924–936. Bibcode:2015NatNa..10..924Z. doi:10.1038/nnano.2015.251.
- ^ Haase, M.; Schäfer, H. Upconverting Nanoparticles. Angewandte Chemie International Edition. 2011, 50: 5808–5829. doi:10.1002/anie.201005159.
- ^ Auzel, François. Upconversion and Anti-Stokes Processes with f and d Ions in Solids. Chemical Reviews. 2004, 104 (1): 139–174. PMID 14719973. doi:10.1021/cr020357g.
- ^ Gamelin, Daniel R.; Güdel, Hans U. Design of Luminescent Inorganic Materials: New Photophysical Processes Studied by Optical Spectroscopy. Accounts of Chemical Research. 2000, 33 (4): 235–242. doi:10.1021/ar990102y.
- ^ Huang, Zhiyuan; Li, Xin; Mahboub, Melika; Hanson, Kerry M.; Nichols, Valerie M.; Le, Hoang; Tang, Ming L.; Bardeen, Christopher J. Hybrid Molecule–Nanocrystal Photon Upconversion Across the Visible and Near-Infrared. Nano Letters. 2015-08-12, 15 (8): 5552–5557. Bibcode:2015NanoL..15.5552H. ISSN 1530-6984. PMID 26161875. doi:10.1021/acs.nanolett.5b02130.
- ^ Wu, Mengfei; Congreve, Daniel N.; Wilson, Mark W. B.; Jean, Joel; Geva, Nadav; Welborn, Matthew; Van Voorhis, Troy; Bulović, Vladimir; Bawendi, Moungi G. Solid-state infrared-to-visible upconversion sensitized by colloidal nanocrystals. Nature Photonics. 2015-11-23, 10: 31–34. Bibcode:2016NaPho..10...31W. ISSN 1749-4893. doi:10.1038/nphoton.2015.226.